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SMAc Team

@lcc-smac.bsky.social

We are a team of chemists exploring reactive organometallic and main-group species to activate small molecules and strong bonds, based at the Laboratory for Coordination Chemistry in the lovely city of Toulouse, France.

132 Followers  |  164 Following  |  43 Posts  |  Joined: 07.02.2025
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Posts by SMAc Team (@lcc-smac.bsky.social)

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Synergistic C–H bond activation across molybdenum–iridium multiply bonded complexes: a cascade of transformations Heterobimetallic compounds offer unique opportunities for activating substrates through cooperative interactions between two distinct metal centers, potentially leading to catalytic reactivity beyond ...

Our article describing the preparation and reactivity of new molybdenum-iridium compounds has been selected as "2025 most popular inorganic chemistry articles" by @chemicalscience.rsc.org !

If you have not seen yet, here you go:
pubs.rsc.org/en/content/a...

#inorganic #organometallic #chemistry

19.02.2026 18:30 β€” πŸ‘ 13    πŸ” 3    πŸ’¬ 0    πŸ“Œ 1

Beautiful work.

18.02.2026 10:14 β€” πŸ‘ 0    πŸ” 0    πŸ’¬ 0    πŸ“Œ 0
Reductive Disproportionation of CO2 Beyond Redox Limits Enabled by Lewis Acid-Coupled Electron Transfer | ChemRxiv A frustrated redox triad comprising Al(C6F5)3 (AlCF), CO2, and decamethylferrocene (FeCp*2) promotes reductive disproportionation of CO2 to CO and carbonate under ambient conditions. Spectroscopic and computational data show that a Lewis acid-bound CO2 ...

New work from the group online on @chemrxiv.org! We describe how Lewis Acid-Coupled Electron Transfer enables COβ‚‚ reductive disproportionation with a very mild reductant. The mechanism implies Cp* non-innocence towards COβ‚‚, highly unusual. Bravo LΓ©on for this nice study!
chemrxiv.org/doi/full/10....

05.02.2026 11:30 β€” πŸ‘ 1    πŸ” 1    πŸ’¬ 0    πŸ“Œ 0

Nice work, congrats Marcus and the team!

05.02.2026 09:34 β€” πŸ‘ 1    πŸ” 0    πŸ’¬ 0    πŸ“Œ 0

Well defined Cs organophosphides rocketing into prominence in alkene isomerisation catalysis with Astronauts Felix and Tom!

20.01.2026 21:01 β€” πŸ‘ 13    πŸ” 2    πŸ’¬ 1    πŸ“Œ 0
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Description Please note that job descriptions are not exhaustive, and you may be asked to take on additional duties that align with the key responsibilities ment...

Currently advertising a three-year PDRA position in organometallic chemistry. Come and work with us @imperialchemistry.bsky.social: www.imperial.ac.uk/jobs/search-...

16.01.2026 10:55 β€” πŸ‘ 16    πŸ” 13    πŸ’¬ 0    πŸ“Œ 1

The group will soon be advertising a 3-year PDRA position @imperialchemistry.bsky.social. The successful candidate will research the synthesis and reactivity of complexes with alkaline earth-metal bonds. Start date: 03/26. Please get in touch for infomal inquries.

08.01.2026 15:26 β€” πŸ‘ 18    πŸ” 18    πŸ’¬ 0    πŸ“Œ 0
Job Details

We're Hiring! If you are interested in a PDRA post with the Mehta group, please apply! @ox.ac.uk @oxfordchemistry.bsky.social

my.corehr.com/pls/uoxrecru...

12.01.2026 12:09 β€” πŸ‘ 10    πŸ” 17    πŸ’¬ 0    πŸ“Œ 0

Congrats Marcus & the team!

07.01.2026 08:16 β€” πŸ‘ 0    πŸ” 0    πŸ’¬ 0    πŸ“Œ 0
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πŸš€Happy New Year!

Our latest work on boron-based batteries is out now!

"Boron-Formazanate Complexes as Tunable Redox-Active Materials for Non-Aqueous Redox Flow Batteries”

Published in @chemistryeurope.bsky.social w/ Joe Gilroy & Edwin Otten! πŸ’ͺ

@westernu.ca @western-chemistry.bsky.social

06.01.2026 13:28 β€” πŸ‘ 14    πŸ” 4    πŸ’¬ 2    πŸ“Œ 0

Just 4 weeks left to apply for the PhD position in our research group! Deadline: 31 January. Don’t miss out, apply today :)

05.01.2026 10:05 β€” πŸ‘ 5    πŸ” 9    πŸ’¬ 0    πŸ“Œ 0

➑️ IPCM News: ipcm.fr/en/postdoc-p...

πŸ“’ PostDoc position available – MACO : Organic and main group chemistry

πŸ“† Duration : 18 months, April st, 2026
πŸ“ @ipcm-sorbonne.bsky.social

Project supervisor : ClΓ©ment Chauvier

@sorbonne-universite.fr @cnrs-paris.bsky.social

16.12.2025 13:05 β€” πŸ‘ 3    πŸ” 3    πŸ’¬ 0    πŸ“Œ 0
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We are hiring two PhDs on our EU SMOM project for a late Sept 2026 start.

The projects will involve being trained, & becoming expert in, air sensitive, platinum group metal organometallics, single-crystal SMOM synthesis, reactivity, and deployment in sustainable catalysis.

See: lnkd.in/emu2Bjzr

17.12.2025 06:50 β€” πŸ‘ 3    πŸ” 2    πŸ’¬ 0    πŸ“Œ 0
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N-centered, yet persistent: isolation of N2O-based radicals through FLP-type stabilization ( @lcc-smac.bsky.social ): pubs.rsc.org/en/content/a... ( @chemicalscience.rsc.org ).

16.12.2025 21:05 β€” πŸ‘ 11    πŸ” 4    πŸ’¬ 0    πŸ“Œ 0
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PhD in Chemistry: Single or Double? A Radical Approach to Catalysis - Competitive EPSRC funded post at Cardiff University on FindAPhD.com PhD Project - PhD in Chemistry: Single or Double? A Radical Approach to Catalysis - Competitive EPSRC funded post at Cardiff University, listed on FindAPhD.com

We’re looking for an enthusiastic PhD student to join our vibrant research group. We have an opening for a PhD position to work on radical Frustrated Lewis pairs. Check out the link below for more information and contacts. ⬇️⬇️⬇️ www.findaphd.com/phds/project...

13.12.2025 06:03 β€” πŸ‘ 14    πŸ” 11    πŸ’¬ 0    πŸ“Œ 0

A new contribution from the group. Congrats Nicolas and Andrea!

12.12.2025 12:40 β€” πŸ‘ 9    πŸ” 0    πŸ’¬ 0    πŸ“Œ 0

Congrats Marcus !

09.12.2025 13:42 β€” πŸ‘ 1    πŸ” 0    πŸ’¬ 0    πŸ“Œ 0

What happens when you put 3 redox-active metal centers together? πŸ§ͺ

@lapluhp.bsky.social demonstrates the simultaneous, cooperative activation of an alkene and dihydrogen in a single complex 🀯

Plus, in-depth kinetic analyses and catalysis. Beautiful work Till!

06.12.2025 10:57 β€” πŸ‘ 19    πŸ” 3    πŸ’¬ 2    πŸ“Œ 0
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Super proud of this little study! Light activated H2 reductive elimination in a Niobium-iridium hydrido cluster.
It was a fun 2 year stay in the Camp Lab, now onto (very) different things!
Thanks for having me! @clementcamp.bsky.social

@daltontrans.rsc.org

pubs.rsc.org/en/content/a...

08.12.2025 20:38 β€” πŸ‘ 7    πŸ” 2    πŸ’¬ 0    πŸ“Œ 0

Congratulations Rebecca!

09.12.2025 13:37 β€” πŸ‘ 1    πŸ” 0    πŸ’¬ 1    πŸ“Œ 0
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Air and water-persistent C-centered radical anion based on FLP-activated CO2 Organic radicals play pivotal roles across chemistry, biology, and materials science. Although typically short-lived and highly reactive, considerable efforts have been devoted to stabilizing open-she...

New work online, check out a new air and water-persistent radical anion based on CO2
chemrxiv.org/engage/chemr...

04.12.2025 14:14 β€” πŸ‘ 3    πŸ” 0    πŸ’¬ 0    πŸ“Œ 0
A Heterometallic Οƒ-Silane Adduct from Cooperative Reactivity of an Iron–Aluminium Complex Protonation of a heterometallic silanide complex with an alcohol led to formation of a Οƒ-silane complex. This reaction does not require a strong acid or weakly coordinating anion. Both metals of the h...

Our latest paper from @benedekstdlr.bsky.social using metal-metal cooperation to access silane complexes is now out in
@chemcomm.rsc.org here is the link pubs.rsc.org/en/content/a...

02.12.2025 09:41 β€” πŸ‘ 10    πŸ” 3    πŸ’¬ 0    πŸ“Œ 1
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The CNRS is breaking free from the Web of Science From January 1st 2026, the CNRS will cut access to one of the largest commercial bibliometric databases, Clarivate Analytics'

From January 1st 2026, the CNRS will cut access to one of the largest commercial bibliometric databases, Clarivate Analytics' Web of Science, along with the Core Collection and Journal Citation Reports.

01.12.2025 11:04 β€” πŸ‘ 85    πŸ” 65    πŸ’¬ 0    πŸ“Œ 25
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Alkene Hydrogenation by a Cationic, Nine-Coordinate Molybdenum(VI) Pentahydride Catalyst The cationic nine-coordinate pentahydrido complex [MoH5(depe)2]BPh4 (1Β·BPh4, depe = 1,2-(diethylphosphino)ethane) is, to the best of our knowledge, the first early transition metal polyhydride shown t...

Our first results on molybdenum polyhydride-catalyzed hydrogenation are out on ChemRxiv. Early-metal polyhydrides can serve as genuine catalysts rather than mere curiosities... chemrxiv.org/engage/chemr...

01.12.2025 15:21 β€” πŸ‘ 1    πŸ” 0    πŸ’¬ 0    πŸ“Œ 0
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A Crystalline Phosphorus-Substituted Borinium Ion: Double Dihydrogen Activation by an Ambiphilic Inorganic Allene ( @chemicalscience.rsc.org ): pubs.rsc.org/en/content/a....

18.11.2025 20:05 β€” πŸ‘ 12    πŸ” 4    πŸ’¬ 0    πŸ“Œ 0
ChemComm The journal for urgent communications of outstanding significance from across the chemical sciences.

ChemComm’s new 5-page limit is here! We’re giving authors more space for statements and references, while preserving the concise and accessible nature of our Communications.

Read our updated guidelines: www.rsc.org/publishing/p...

18.11.2025 10:17 β€” πŸ‘ 17    πŸ” 13    πŸ’¬ 0    πŸ“Œ 1

Great news, congratulations Josef.

17.11.2025 11:32 β€” πŸ‘ 1    πŸ” 0    πŸ’¬ 0    πŸ“Œ 0

Bravo d'abord aux deux Γ©quipes de Paris et de Toulouse

14.11.2025 13:23 β€” πŸ‘ 1    πŸ” 0    πŸ’¬ 0    πŸ“Œ 0
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Comment transformer du COβ‚‚Β en sucres Dans une Γ©tude publiΓ©e dans « Chemical ScienceΒ Β» le 23Β octobre, des chercheurs dΓ©voilent la recette pour transformer des gaz nocifs en sucres. Une technique qui pourrait amener certaines productions v...

Read more about @emoca-ipcm.bsky.social recent paper in @lemonde.fr @ipcm-sorbonne.bsky.social @lcc-cnrs.bsky.social @lcc-smac.bsky.social
www.lemonde.fr/sciences/art...

14.11.2025 08:48 β€” πŸ‘ 5    πŸ” 2    πŸ’¬ 0    πŸ“Œ 1
Graphical abstract image for β€œCO-to-Sugars Conversion from One-Pot Two-Step Electro-Organocatalytic Process” by Julien Bonin, Marc Robert and SΓ©bastien Bontemps et al.

Graphical abstract image for β€œCO-to-Sugars Conversion from One-Pot Two-Step Electro-Organocatalytic Process” by Julien Bonin, Marc Robert and SΓ©bastien Bontemps et al.

πŸ”₯ New and HOT in Chemical Science!

β€œCO-to-Sugars Conversion from One-Pot Two-Step Electro-Organocatalytic Process” by Julien Bonin, Marc Robert and SΓ©bastien Bontemps et al.

Read it for free: doi.org/10.1039/D5SC...

#ChemSky #ChemSciHOT

13.11.2025 16:00 β€” πŸ‘ 2    πŸ” 1    πŸ’¬ 0    πŸ“Œ 0