eMOCA@IPCM @emoca-ipcm - Bluesky Profile

New post: [Job] Post-doctoral Fellowship in Electrochemical generation of reactive Nitrido complexes for Nitrogen Atom Transfer https://frenchbic.cnrs.fr/2025/06/23/post-doctoral-fellowship-in-electrochemical-generation-of-reactive-nitrido-complexes-for-nitrogen-atom-transfer/

23.06.2025 17:49 — 👍 0 🔁 1 💬 0 📌 0

⚡🌩️ From molecular to flow-cell: Our latest paper shows cobalt(III)triphenylcorrole for CO2 reduction to CO and methanol now out in ACS Catalysis.
In collaboration with ICMUB bourgogne

congratulations @afrza686.bsky.social @ajeetsinghm.bsky.social Bishnu and Marcello
@ipcm-sorbonne.bsky.social

17.06.2025 08:11 — 👍 2 🔁 4 💬 0 📌 0

➡️Actu IPCM : ipcm.fr/en/latest-pu...

📜👍Latest publication – @emoca-ipcm.bsky.social group
Self-Photosensitizing Cobalt Complexes for Photocatalytic CO2 Reduction Coupled with CH3OH Oxidation
Angewandte Chemie

@sorbonne-universite.fr @cnrs-paris.bsky.social

26.05.2025 11:35 — 👍 0 🔁 1 💬 0 📌 0

Direct Synthesis of Polyesterether from Ethylene Glycol We report here a method for making polyesterether from ethylene glycol. The reaction is catalyzed by a ruthenium complex and liberates H2 gas and H2O as byproducts. Mechanistic studies conducted throu...

Always great working with @kumarlabsta.bsky.social
Check out latest work on green ethylene glycol dehydrogenative polymerisation 🔗💧🌿 @emoca-ipcm.bsky.social @ipcm-sorbonne.bsky.social @uniofstandrews.bsky.social @cnrs.fr
pubs.acs.org/doi/10.1021/...

12.04.2025 12:01 — 👍 3 🔁 4 💬 1 📌 0

New post: [Job] PhD: From O2 electrochemical activation to the development of sustainable oxidation processes of organic substrates https://frenchbic.cnrs.fr/2025/04/10/phd-from-o2-electrochemical-activation-to-the-development-of-sustainable-oxidation-processes-of-organic-substrates/

10.04.2025 13:51 — 👍 2 🔁 1 💬 0 📌 0

Thesis offer (eMOCA group) – From O2 electrochemical activation to the development of sustainable oxidation processes of organic substrates – Parisian Institute of Molecular Chemistry – UMR 8232 Oxidation chemistry in industrial processes constitutes a multimegaton commodity production valuing tens of billions dollars. The current economic and environmental contexts require to urgently replace the energy-demanding and harmful technologies often used with economically viable and environmentally sound alternatives.1 Through the reductive activation of O2, metalloenzymes, such as heme and nonheme Fe oxygenases achieve efficient and selective oxygenations by unravelling O2 oxidizing power. This is achieved through partial and controlled reduction of O2 bound at the Fe active site, involving sequential e– and H+ transfers to the Fe-oxygen adduct and formation of various oxidizing intermediates during the catalytic cycle.2 We have developed an electrochemical reductive O2 activation strategy and succeeded in mimicking the oxygenase activity by using Fe and Mn porphyrins to generate and to characterize various M-oxygen oxidizing species3 and to tune their reactivity.4 This original approach is part of the development of green electrosynthesis in an effort to electrify homogeneous catalysis.5

📢 We are hiring‼️ One #PhD fellowship available in the electrochemical O2 activation for organic synthesis. Don't miss the opportunity to join us! Check details👇
@emoca-ipcm.bsky.social @ipcm-sorbonne.bsky.social @sorbonne-universite.fr

#phdposition #Electrochemistry #Paris

10.04.2025 15:43 — 👍 0 🔁 2 💬 1 📌 0

In‐Situ Constructing Eosin Y Sensitized Cs2PtSnCl6 Perovskites for Enhanced Photocatalytic Hydrogen Evolution An innovative in situ synthesis method to construct EY-Cs2PtSnCl6 material for photocatalytic HER has been designed. The EY-Cs2PtSnCl6 achieved an impressive HER rate of 17.6 mmol g−1 h−1 in aqueous ...

Check out our recent paper about Photocatalytic Hydrogen Evolution using perovskites. In collaboration with Zhejiang team in China.

#Chemsky #HER #perovskites #Photoelectrochemical

10.04.2025 15:37 — 👍 0 🔁 1 💬 0 📌 0

Hybrid CIGS‐Cobalt Quaterpyridine Photocathode with Backside Illumination: a New Paradigm for Solar Fuel Production Chalcogenide-based thin-film solar cell optimized for rear illumination and used for CO2 reduction is presented. Central to this innovation is a thinner, Cu(In,Ga)S2 chalcopyrite absorber coated with...

Happy new year 2025!

With our new home, we are happy to share our first paper about new method for preparing PEC devices. In collaboration with CEISAM lab in Nantes. Congratulations Deba and Paulo!
#Chemsky #Artificialphotosynthesis #CO2RR #Photoelectrochemical

14.01.2025 14:22 — 👍 5 🔁 3 💬 0 📌 0

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