Ghadwal Research Group

Bicyclo[1.1.0]tetragermane‐2,4‐diide Diradicaloid The bicyclo[1.1.0]tetragermane-2,4-diide diradicaloid compound [(ADC)2Ge4] featuring a stretched bridgehead Ge─Ge bond is reported as a Venetian red crystalline solid. [(ADC)2Ge4] has been characteri...

Pleased to share Falk’s latest work @ghadwalgroup.bsky.social on a non-classical germanium diradicaloid, just published in @angewandtechemie.bsky.social highlighting a new approach (using anionic dicarbenes) to main-group diradicaloids: onlinelibrary.wiley.com/doi/10.1002/... thanks to @dfg.de

The Hudnall lab is hiring a Postdoctoral Fellow! Applicants excited about joining our recently relocated research group and interested in the synthesis of exotic main-group molecules, materials and heterodiatomics can email Dr. Hudnall directly. Please share!

Understanding Small Molecule Activation Promoted by Heavier Benzene 1,4‐diides: Interplay between Diradical Character and Aromaticity The intricate relationship between diradical character, aromaticity, and reactivity in annulated heavier Group 14 benzene-1,4-diides, i.e. [(ADC)E]2 (E = Si, Ge, Sn), based on an anionic dicarbene fr...

Check out our work just accepted in @chemistryeurope.bsky.social (ChemEurJ) on Understanding Small Molecule Activation by Heavier Benzene 1,4‐diides: Interplay between Diradical Character and Aromaticity @ghadwalgroup.bsky.social chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/...

Reversible single-electron-transfer (SET) in #maingroup systems—cyclic pnictogen radicals—analogs of aryl radical anions in Birch reductions— @angewandtechemie.bsky.social Congratulations to Henric and all @ghadwalgroup.bsky.social
@basdebruin.bsky.social onlinelibrary.wiley.com/doi/10.1002/...

And already cited 🤔 congrats

Paneth’s mirrors and the isolation of methyl radicals Laying the groundwork for the study of combustion and photochemical reactions

Paneth’s mirrors and the isolation of methyl radicals
www.chemistryworld.com/opinion/pane...

Thanks a lot.

Delighted to share the first original research article of 2025 by @ghadwalgroup.bsky.social
... in @angewandtechemie.bsky.social dedicated to @remglasgow.bsky.social

thanks to @dfg.de

👉 Lithium Anionic Dicarbenes or Acetylides: What is in the Name? onlinelibrary.wiley.com/doi/10.1002/...

1,4-Disilabenzenes: Low-Valent Silicon Aromaticity Thieme E-Books & E-Journals

Very happy to share that our research @ghadwalgroup.bsky.social on 1,4-Disilabenzenes @acsjacs.bsky.social has been highlighted in #synfacts:
www.thieme-connect.com/products/ejo...

Structural Snapshots of Reversible Carbon Dioxide Capture and (De)oxygenation at Group 14 Diradicaloids Although diradicals should exhibit a rather small reaction barrier as compared to closed-shell species for activating kinetically inert molecules, the activation and functionalization of carbon dioxid...

Excited to share this fantastic collaboration with
Ghadwal_Group just published in JACS @acspublications.bsky.social on Carbon Dioxide Capture and (De)oxygenation at Group 14 Diradicaloids
pubs.acs.org/doi/10.1021/...

Hi All,
We (Ghadwal Research Group at Uni Bielefeld) are now on @bsky.app and wish you all the best for 2025.
🕊️🫶🌍👐