Defining, designing and determining the structure of supramolecular frameworks
Supramolecular frameworks, ordered porous networks assembled by noncovalent interactions, are a broad class of functional materials with emergent combinations of properties arising from the relatively...
Michael McGuirk and I wrote an tutorial review on supramolecular frameworks (hydrogen bonds, halogen bonds, chalcogen bonds etc) where we try to get everyone to agree on some common definitions for things. Might be a long shot!
Hopefully useful for new students.
pubs.rsc.org/en/content/a...
29.09.2025 03:52 β π 12 π 2 π¬ 0 π 0
Low Symmetry Cage Complexes Formed by Metalation of Symmetric HexaβCationic Organic Cages
Threefold symmetric hexa-cationic hydrazone cages coordinate a range of transition metal ions upon deprotonation. When the cage contains ethyl solubilising groups the expected threefold symmetric cag...
We have a new paper out with Annie Colebatch: we metalate 6+ hydrazone cages to give M3-cage metallocages with coordinatively unsaturated metal ions. Et solubilising groups give expected 3-fold symmetric metallocages. OMe or OPr give funky low-symmetry cages tinyurl.com/4ehppaex.
21.08.2025 21:58 β π 12 π 3 π¬ 0 π 0
Very good thread on the silliness of impact factors.
13.08.2025 22:02 β π 4 π 0 π¬ 0 π 0
To be honest I think there's a space for both. Some unis all online, some all in-person. If we are going to do online lectures though, why does every uni need to make their own? Why not just get a few good lecturers to make videos for everyone?
25.07.2025 08:44 β π 0 π 0 π¬ 2 π 0
Or stop giving out lecture recordings to everyone? Could be given to people with a medical need, or to everyone in exam period?
24.07.2025 09:04 β π 1 π 0 π¬ 1 π 0
I think you overestimate the political engaged-ness of the average voter and the inherent tendency to vote for a) who they voted for last time and/or b) one of the two majors by default.
I know you acknowledged that, so consider this a pointless response to your pointless punditry prediction.
02.07.2025 07:13 β π 1 π 0 π¬ 0 π 0
Sadly I suspect you're right.
24.06.2025 02:00 β π 0 π 0 π¬ 0 π 0
Yeh I agree. I think speed of publication is also one of the reasons materials journals have such IFs - it's quicker to turn work around than say a natural product synthesis or a protein evolution study.
24.06.2025 02:00 β π 2 π 0 π¬ 0 π 0
Is this because theyβre publishing more of the better papers? Or just focusing on highly cited areas? Or that people are getting lazy with their citing and just concentrating on JACS/Angew? Possibly all of the above?
23.06.2025 23:28 β π 5 π 0 π¬ 2 π 0
So what does this all mean? Probably not much. The very top journals are cannibalising the next tier down as well as the subdiscipline-specific journals (JOC, Inorg. Chem. etc).
23.06.2025 23:28 β π 3 π 0 π¬ 2 π 0
Theyβre cut off from my graph, but Nat. Chem. (22 --> 20) and Chem (20 --> 20) have stayed broadly similar. Nature (43 --> 49), Science (42 --> 46) have increased slightly.
23.06.2025 23:28 β π 0 π 0 π¬ 1 π 0
Pleasingly this year, there are lots of papers that have been cited a few times, which seems more sustainable! (Each paper only contributes to IFs for the year it is published and the following year).
23.06.2025 23:28 β π 0 π 0 π¬ 1 π 0
On a personal note, Supramol. Chem. has increased from 1.3 --> 2.6 in this time. This probably says something about the vagaries of IFs though: a couple of years ago, it was even higher (3.3), in that case largely based on one very highly-cited paper.
23.06.2025 23:28 β π 2 π 0 π¬ 1 π 0
In both years, materials IFs >> inorganic > organic ~ phys chem.
23.06.2025 23:28 β π 1 π 0 π¬ 1 π 0
My suspicion is that this is because these journals are publishing a lot of highly/rapidly citing materials chemistry, but I donβt really know. It could be the effects of being open access too, or that there is a lot of useful stuff in these journals.
23.06.2025 23:28 β π 4 π 0 π¬ 1 π 0
The other journals that have improved a lot are RSC Adv., ACS Omega and Molecules. This means that the ACS and RSC βless-selectiveβ journals now have higher IFs than e.g. JOC, Dalton, OBC. This isnβt just that theyβre publishing more reviews.
23.06.2025 23:28 β π 3 π 0 π¬ 1 π 0
JACS, Angew and Nat. Comm. are notable improvers, while what I would consider the next tier down from JACS/Angew (Chem. Sci., Chem. Comm. CEJ) have decreased quite a lot. That means the gap between JACS/Angew and the rest is pretty huge.
23.06.2025 23:28 β π 4 π 0 π¬ 2 π 0
A graph comparing 2024 and 2019 journal impact factors.
IFs are clearly silly and game-able, and I donβt think they have that much of a correlation with βquality,β but itβs interesting (to me) to see how theyβre changing over time. This chart compares 2019 and 2024 IFs: things above the black line have increased, below have decreased.
23.06.2025 23:28 β π 10 π 1 π¬ 1 π 1
2024 journal impact factors are out, and I had a bit of a play around comparing the numbers with 2019 IFs. Bit of a thread to follow, but general trend seems to be most journal IFs are trending downward but JACS/Angew and big βless-selectiveβ journals buck the trend.
23.06.2025 23:28 β π 27 π 6 π¬ 3 π 4
Yeh it's weird here - everyone is nice but no one really engages much.
Although the next post in my timeline is a thread with loads of people debating how to capitalise UV-Vis...so maybe there's still hope?
13.06.2025 20:46 β π 2 π 0 π¬ 1 π 0
Research Fellow - School of Chemistry - 105878 - Grade 7
To create and contribute to the creation of knowledge by undertaking a specified range of activities within an established research programme and/or specific research project.
We have a 3-year postdoc position available, starting in October, to work on molecular capsules for catalysis. Click on the link below to apply! π Happy to have informal chats about the post - send me an email. Application deadline 6 July. edzz.fa.em3.oraclecloud.com/hcmUI/Candid... #chemsky
13.06.2025 15:38 β π 13 π 19 π¬ 0 π 0
Annoyingly, the Chrome extension has been disabled (doesn't follow Chrome best practice guidelines, apparently).
11.05.2025 22:40 β π 1 π 0 π¬ 2 π 0
Awesome, will give that a shot - thanks!
09.05.2025 08:33 β π 1 π 0 π¬ 0 π 0
Does anyone tech-savvy know if there's a browser extension or something that get journals to just show me the normal pdf rather than their annoying epdfs?
Manually deleting the e from epdf in the web address and reloading is getting tedious.
#chemsky
08.05.2025 22:05 β π 3 π 0 π¬ 1 π 0
πππ This one is in a good journal - it seems like someone from the editorial/production team should probably have caught it!
09.04.2025 23:44 β π 1 π 0 π¬ 0 π 0
Journal article title: The facile preparation of mixed-valence mental-organic frameworks through reduction
Who among us hasn't wanted to prepare a "mental-organic framework?" #chemsky
09.04.2025 05:20 β π 52 π 6 π¬ 3 π 1
Bit belated (thanks COVID), but thanks to everyone who came to Supramol25 in Canberra last week. Some great plenaries and prize talks, and most impressively of the ~ 30 talks over 2 days, not a single one was in 4:3 format!
I think this might be a career highlight.
13.02.2025 02:09 β π 6 π 1 π¬ 0 π 0
Not sure the link is working @jona-foster.bsky.social
17.01.2025 09:02 β π 0 π 0 π¬ 0 π 0
Please could I jump on this. @prestongroup.bsky.social should probably be there too.
08.01.2025 06:29 β π 2 π 0 π¬ 1 π 0
Not my intention I promise!
23.12.2024 05:29 β π 0 π 0 π¬ 0 π 0
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Professor of Chemistry, UniversitΓ degli Studi di Milano, passionate on fluorescence organic dyes