GoicoecheaGroup

Welcome to Bloomington, Kike!

Congratulations, Lucas! Fantastic work!!!

Check out the latest from Team GG alumnus, Chenyang Hu, out today in @chemicalscience.rsc.org! We report on the synthesis and isolation of an unsupported phosphinidene sulfide and selenide. Follow the link for some super cool chemistry performed expertly by Chenyang!

pubs.rsc.org/en/content/a...

Congratulations, Barry. Richly deserved!

The Hudnall lab is hiring a Postdoctoral Fellow! Applicants excited about joining our recently relocated research group and interested in the synthesis of exotic main-group molecules, materials and heterodiatomics can email Dr. Hudnall directly. Please share!

Stepwise Acetylene Insertion and Ammonia Activation at a Digallene and Diindene Sequential [2+2] cycloaddition reactions between acetylene and the digallene and diindene compounds (ETer)2 (E = Ga, In; Ter = 2,6-Dipp2-C6H3; Dipp = 2,6-diisopropylphenyl) are described. Careful con...

PDRA extraordinaire, Álvaro García-Romero, hits it out if the park again! Check out his most recent work out today in @angewandtechemie.bsky.social. Outstanding computational support by DFT master @isra-group.bsky.social! Further details here: onlinelibrary.wiley.com/doi/10.1002/...

Congratulations once again, Josh! I’m sure you’ll flourish at Manchester. Well done.

Thrilled to share that the Szych research group kicks off this June, thanks to a Liebig fellowship from @chemieverband.bsky.social 🥳 Huge thanks to all my mentors! 😊

You are a motivated master's student and interested in a fully funded PhD position in inorganic chemistry? Reach out! 🧑‍🔬👩‍🔬

Reversible Decarbonylation of a Metal Phosphaketene We describe the synthesis of a metalated phosphastannene by reaction of the known cobalt(I) phosphaketene complex Co(DippPDI)(PCO) (DippPDI = 1,1'-(pyridine-2,6-diyl)bis(N-(2,6-diisopropylphenyl)etha...

Check out the latest research by Goicoechea group alumnus (and penultimate of our Oxford-based graduate students) Matt Reveley! Out today in @chemistryeurope.bsky.social. We report on the highly unusual chemistry of a metallated phosphastannene. Some stellar work by Matt and Joey, as usual.

Well done, Eric! Congratulations!

Happy to share that I’ve been selected to join the RCSA Fellows! I look forward to being a part of the program with @rescorp.org.

Mark your calendars for a thought provoking Solid-State Periodic TableTalks (Wednesday 4/16 at 12 pm PST/ 3pm EST) featuring Maxx Arguilla (@maxxsolidchem.bsky.social, UCIrvine) and Susan Kauzlarich (UCDavis). Register here:
unr.zoom.us/meeting/regi... @acs.org

Quite the turnout. Hope you had fun!

Enjoy the meeting! Have a slice on my behalf.

A Fresh Twist on the Phospha-(Aza)-Wittig Reaction The reactivity of an unsupported phosphinidene oxide, BnArNP═O (Bn = benzyl; Ar = bulky aryl group), as the electrophilic partner in Wittig reactions with ylides is described. Reactions with methylene-triphenylphosphorane (H2C═PPh3) and ethylidene-triphenyl-phosphorane (HMeC═PPh3), proceed as expected, giving rise to the phosphaalkene metathesis products and triphenylphosphine oxide. This reaction can be extended to other ylides such as N-(triphenylphosphoranylidene)methanamine (MeN═PPh3), to afford an aminoiminophosphane BnArNP═NMe. In these reactions the phosphinidene oxide plays the role of an electrophile, which would typically be the remit of an organic carbonyl in classical Wittig reactions. Further mechanistic insight into such transformations can be gained by altering the nature of the phosphorus-ylide. Upon reacting BnArNP═O with H2C═PMe3 (which possesses a smaller, more Lewis basic, phosphine) an alternative product is formed. This transformation supports the formation of a betaine intermediate that subsequently undergoes hydrogen-migration to afford an oxidized phosphorus(V) compound related to phosphorus acid.

Fresh out of the oven. Check out Chenyang’s most recent work in JACS (@jacs.acspublications.org). We explore the reactivity of a phosphinidene oxide as the electrophilic partner in Wittig transformations. Hope you enjoy.

pubs.acs.org/doi/full/10....

Check, check. All transmitters to full. All receivers to boost. The Goicoechea Group is transmitting on an alternate frequency. Is anyone out there?