Fielding Group

Rate constants and Arrhenius parameters for H-atom abstraction from Bu3SnH by the 2,2-dimethylvinyl radical in PhMe. Kinetic evidence for an entirely free radical mechanism for the O-directed hydrostannation of alkynols with stannanes and Et3B/O2 Using the 2,2-dimethylvinyl radical 6 as a horological calibrant for the α-cyclopropyl-β-tributylstannylvinyl radicals 2a and 13 in PhMe, the k values and Arrhenius parameters for their cyclopropane…

🔓Don't miss this #OpenAccess paper by Alistair J. Fielding, Karl J. Hale & co @qubelfastofficial.bsky.social showing kinetic evidence for an entirely free radical mechanism for the O-directed hydrostannation of alkynols with stannanes and Et3B/O2 #orgchem

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pubs.rsc.org/en/content/a...

Rate constants and Arrhenius parameters for H-atom abstraction from Bu3SnH by the 2,2-dimethylvinyl radical in PhMe. Kinetic evidence for an entirely free radical mechanism for the O-directed hydrosta... Using the 2,2-dimethylvinyl radical 6 as a horological calibrant for the α-cyclopropyl-β-tributylstannylvinyl radicals 2a and 13 in PhMe, the k values and Arrhenius parameters for their cyclopropane r...

pubs.rsc.org/en/content/a...

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