Alex J. Stirk's Avatar

Alex J. Stirk

@alexjstirk.bsky.social

Ph.D in rotaxane containing MOFs. Now in solid state pharma. Interested in all things solid state and interlocked.

455 Followers  |  490 Following  |  67 Posts  |  Joined: 19.11.2024  |  1.8269

Latest posts by alexjstirk.bsky.social on Bluesky

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Taken me so long to get to this point of owning my own board, but it's here! Torq 9'1". All waxed and ready to go on its maiden voyage!

02.08.2025 14:44 โ€” ๐Ÿ‘ 1    ๐Ÿ” 0    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0
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TIL that you can get hydrochloric acid like this. I have no idea why we bought this. Itโ€™s giving boxed wine / to-go vibes.

11.07.2025 16:57 โ€” ๐Ÿ‘ 29    ๐Ÿ” 4    ๐Ÿ’ฌ 3    ๐Ÿ“Œ 1

To all of those going to ICCOSS '25. Just know that I'm extremely jealous and dying of envy.
I hope none of your projector adaptors work and they reschedule it to a more convenient date for me.

10.07.2025 20:15 โ€” ๐Ÿ‘ 0    ๐Ÿ” 0    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0
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New Stirk just dropped. She's so little! Mom is doing great. Looking forward to taking a break from chemistry for a little bit!

04.06.2025 14:21 โ€” ๐Ÿ‘ 4    ๐Ÿ” 0    ๐Ÿ’ฌ 1    ๐Ÿ“Œ 0
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14.05.2025 22:27 โ€” ๐Ÿ‘ 17    ๐Ÿ” 1    ๐Ÿ’ฌ 2    ๐Ÿ“Œ 0
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๐Ÿ”—Medieval Chainmail meets Modern Materials! Our 2D [c2]daisy chain polymer (think: molecular-scale armor!) self-assembles into chainmail-like networks, achieving shape-shifting superpowers under stimuli.
โšก๏ธ Breakthrough for soft robotics & smart textiles! #MaterialsScience
๐Ÿ‘‰https://rdcu.be/ehOa6

15.04.2025 11:15 โ€” ๐Ÿ‘ 68    ๐Ÿ” 17    ๐Ÿ’ฌ 7    ๐Ÿ“Œ 7

This is great work. Some in the Loeb group back between 2013-2017 were trying ever so hard to get reliable daisy chains to work. It mostly the imidazole templating route. There's an MSc thesis from 2015 that a lot of work was done on this. Glad to see that daisy chains are sill of interest!

11.05.2025 17:43 โ€” ๐Ÿ‘ 0    ๐Ÿ” 0    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0

Cursed chemdraw.

01.05.2025 12:35 โ€” ๐Ÿ‘ 0    ๐Ÿ” 0    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0

I miss this field a lot.๐Ÿ˜ž

29.04.2025 21:20 โ€” ๐Ÿ‘ 0    ๐Ÿ” 0    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0
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Molecular machines won a Nobel prize nine years ago, but we still canโ€™t decide what one is World authority on chemistry nomenclature aims to clean up molecular machine terminology

www.chemistryworld.com/news/molecul...

29.04.2025 17:39 โ€” ๐Ÿ‘ 3    ๐Ÿ” 1    ๐Ÿ’ฌ 1    ๐Ÿ“Œ 1

So far, so good. I had it on the maximum 650 rpm with two 3 mm balls and no breakages. I broke one vial though when I stuffed in 10 ร— 3 mm to see what the limit would be.

14.04.2025 20:19 โ€” ๐Ÿ‘ 1    ๐Ÿ” 0    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0
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Het. An adaptor for a planetary mill! Retsch now sells them. Pretty cool!

14.04.2025 20:12 โ€” ๐Ÿ‘ 1    ๐Ÿ” 0    ๐Ÿ’ฌ 1    ๐Ÿ“Œ 0

Not if you have a high throughout system. Just using normal HPLC vials in an adaptor.

14.04.2025 20:06 โ€” ๐Ÿ‘ 0    ๐Ÿ” 0    ๐Ÿ’ฌ 1    ๐Ÿ“Œ 0

SUMMONING #Mechanochemistry

14.04.2025 18:38 โ€” ๐Ÿ‘ 1    ๐Ÿ” 0    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0

I saw one reported as "a speed equivalent to a shaking frequency of 10 Hz.". Which converts to 600 rpm. The limit on my mill is 650 rpm, so that seems very high!

14.04.2025 16:41 โ€” ๐Ÿ‘ 0    ๐Ÿ” 0    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0

Anyone else use a planetary mill for cocrystals?
I'm seeing a wide range of rpm/solvent volume/ball loadings. Anyone have a magic combination?

14.04.2025 16:37 โ€” ๐Ÿ‘ 1    ๐Ÿ” 1    ๐Ÿ’ฌ 3    ๐Ÿ“Œ 0

Remember those patterns? Our article is finally out on @naturecomms.bsky.social and you can read what disordered marvels caused them! Thanks to @nchampness.bsky.social @ellamschmidt.bsky.social & all the great scientists I joined in this journey ๐ŸŽ†
#MOF #crystallography #totalscattering #3DdeltaPDF

04.04.2025 07:49 โ€” ๐Ÿ‘ 30    ๐Ÿ” 9    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 1

Missed this the first time around!

24.03.2025 01:38 โ€” ๐Ÿ‘ 1    ๐Ÿ” 0    ๐Ÿ’ฌ 1    ๐Ÿ“Œ 0
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๐Ÿ‡จ๐Ÿ‡ฆ Come be our colleague! @uottawascience.bsky.social is hiring a supervisor for our X-Ray Core Facility, with new high end equipment coming soon. Ottawa is a beautiful place to live. Please share widely!

10 days left to apply: uottawa.wd3.myworkdayjobs.com/en-US/uOttaw...

17.03.2025 21:14 โ€” ๐Ÿ‘ 18    ๐Ÿ” 15    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 1

I'm not sure I agree, but I do think there is a point here. One could argue that experts in areas from public health to economics to (gasp) political science have been too confident that the public should follow their recommendations because they are 'right'. But that's an odd form of democracy. 4/n

03.03.2025 09:31 โ€” ๐Ÿ‘ 13    ๐Ÿ” 2    ๐Ÿ’ฌ 3    ๐Ÿ“Œ 1

Don't let your memes be dreams. With enough BuLi, anything is possible.

26.02.2025 15:09 โ€” ๐Ÿ‘ 1    ๐Ÿ” 0    ๐Ÿ’ฌ 1    ๐Ÿ“Œ 0

So, hear me out:

25.02.2025 22:36 โ€” ๐Ÿ‘ 15    ๐Ÿ” 3    ๐Ÿ’ฌ 3    ๐Ÿ“Œ 0

What an incredible loss for the crystallography community and science in general. Prof Sheldrick was truly a giant and such a nice person. May he rest in peace ๐Ÿ•ฏ๏ธ

21.02.2025 23:58 โ€” ๐Ÿ‘ 7    ๐Ÿ” 2    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0
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Working-class creatives donโ€™t stand a chance in UK today, leading artists warn Exclusive: Analysis by the Guardian shows a third of major arts leaders were educated privately

Not just artists. Scientists too. Has anyone questioned about who can actually afford to move and do graduate school/post-docs now?

Yes scholarships exist, but sometimes the upfront moving cost is too much.

www.theguardian.com/culture/2025...

21.02.2025 18:14 โ€” ๐Ÿ‘ 0    ๐Ÿ” 0    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0

English is a terrible, yet fantastic language. Many opinions!

19.02.2025 20:18 โ€” ๐Ÿ‘ 0    ๐Ÿ” 0    ๐Ÿ’ฌ 1    ๐Ÿ“Œ 0

Trying to convince the MS Word auto correction that plurals exist.

19.02.2025 19:18 โ€” ๐Ÿ‘ 0    ๐Ÿ” 0    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0

Ok. Now I've seen it corrected as a possessive and non-possesive.
Do you say:"pKas", "pKa's" or pKas'"
In the context of: "their low pKas led to..blah blah".

19.02.2025 18:26 โ€” ๐Ÿ‘ 0    ๐Ÿ” 0    ๐Ÿ’ฌ 5    ๐Ÿ“Œ 0
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Complex structures arising from the self-assembly of a simple organic salt - Nature Frankโ€“Kasper phases are observed in small organic molecules from the crystallization of fampridine hydrochloride into two distinct structures, indicating that complex self-assembled structures can ari...

We are looking for a PhD candidate in Chemistry @UNamur! ๐Ÿงช The project focuses on NMR and X-ray crystallography of complex crystalline phases of simple salts, building on our Nature 2021 work: doi.org/10.1038/s415....
๐Ÿ”— Apply here:
euraxess.ec.europa.eu/jobs/316363
www.linkedin.com/jobs/view/41...

12.02.2025 15:24 โ€” ๐Ÿ‘ 4    ๐Ÿ” 5    ๐Ÿ’ฌ 1    ๐Ÿ“Œ 1
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Supramolecular Chemistry in Metalโ€“Organic Framework Materials This review highlights synergies between reticular chemistry and supramolecular chemistry. The role of supramolecular interactions in determining frameworkโ€ฆguest interactions and attempts to understa...

Delighted to see this review published. We discuss two of my favourite areas of chemistry, MOFs and supramolecular chemistry โ€“ what could be more interesting! Thanks to @eugemiguel.bsky.social , @georgiaorton.bsky.social and Danielle Schier. doi.org/10.1002/adma.202414509

04.02.2025 12:53 โ€” ๐Ÿ‘ 28    ๐Ÿ” 5    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 0
Cartoon representation of a MOF showing various supramolecular interactions and components, including linker-bound metals and catenanes.

Cartoon representation of a MOF showing various supramolecular interactions and components, including linker-bound metals and catenanes.

Our latest review is out on two of our favourite topics! Here we discuss 'chemistry beyond the framework', highlighting the role that Supramolecular Chemistry plays in Metalโ€“Organic Framework Materials.
doi.org/10.1002/adma... @nchampness.bsky.social

03.02.2025 09:05 โ€” ๐Ÿ‘ 28    ๐Ÿ” 9    ๐Ÿ’ฌ 0    ๐Ÿ“Œ 1

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